[rac-2-(1-Aminoethyl)phenyl-κ2 C 1,N](ethylendiamine-κ2 N,N′)palladium(II) 3,5-dimethylbenzoate
نویسندگان
چکیده
In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(9)H(9)O(2)), the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl-enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex and the 3,5-dimethyl-benzoate anion are inter-connected by N-H⋯O hydrogen bonds.
منابع مشابه
[rac-2-(1-Aminoethyl)phenyl-κ2 C 1,N](ethylendiamine-κ2 N,N′)palladium(II) 3-methylbenzoate monohydrate
In the title compound, [Pd(C(8)H(10)N)(C(2)H(8)N(2))](C(8)H(7)O(2))·H(2)O, the palladium ion is coordinated in a distorted square-planar fashion by the two N atoms from the chelating ethyl-enediamine group and by the N and a C atom of the deprotonated chiral amine. The resulting cationic complex, the 3-methyl-benzoate anion and the hydrate water mol-ecule are inter-connected by N-H⋯O and O-H⋯O ...
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The title compound, [Pd(2)(C(13)H(8)N(2)O(2))(C(15)H(11)O(2))(2)], crystallized from a mixture of ethanol and n-hexa-nes. The structure is the first example of β-diketonate in a dianionic κ(2)C-coordination complex containing a Pd(II)-Pd(II) bond. Both Pd(II) atoms adopt a pseudo square-planar coordination geometry. The mol-ecular packing involves π-inter-actions between the phenyl rings of the...
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In the binuclear title complex, [Pd2(C11H13ClN)2Cl(N3)]·CHCl3, each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl-amino-1-phenyl-propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intra-molecular C-H⋯Cl contact in the complex mol-ecule. In the crystal, the chloro-form ...
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In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl-imidazole with dimeric dichloridobis[2-(dimethyl-amino)-benz-yl]palla-dium(II), the ring-deprotonated N,N-dimethyl-benzyl-amine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methyl-imidazole ligand and the palladacycle plane is 57.88 (16)°. The two ...
متن کاملBis(μ-3,5-dinitro-2-oxidobenzoato)-κ3 O 1,O 2:O 1;κ3 O 1:O 1,O 2-bis[aqua(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2 N 7,N 8)cobalt(II)]
In the title compound, [Co(2)(C(7)H(2)N(2)O(7))(2)(C(19)H(12)N(4))(2)(H(2)O)(2)], the Co(II) atom is six-coordinated by two N atoms from a 2-phenyl-1H-1,3,7,8,-tetraaza-cyclo-penta-[l]phenanthrene (L) ligand, three O atoms from two 3,5-dinitro-2-oxidobenzoate (3,5-dinitro-salicylate or DNSA) ligands and one O atom from a water mol-ecule in a distorted octa-hedral geometry. The Co(II) atoms are ...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010